No.118
Synthesis of Metallocene Complexes
| B2281 | 1,2-Bis(3-indenyl)ethane (1) |
5g 1g |
Metallocene complexes, which have group IV elements like Ti, Zr, and Hf as center metals, are used in a variety of reactions both as catalysts for olefin polymerization and as reaction agents for stereoselective reactions.1) Metallocene complexes 2 and 3, having 1,2-bis(3-indenyl)ethane (1) as a ligand, are employed as catalysts for isotactic polymerization of propyrene in the presence of co-catalyst methylaluminoxane (MAO).2)
References
1) Synthesis and applications of chiral cyclopentadienylmetal
complexes
R. L. Halterman, Chem. Rev., 92, 965 (1992).
2) Metallocene catalyst for the isotactic polymerization of propylene
G. M. Diamond, R. F. Jordan, J. L. Petersen, J. Am. Chem. Soc., 118, 8024
(1996).
complexes
R. L. Halterman, Chem. Rev., 92, 965 (1992).
2) Metallocene catalyst for the isotactic polymerization of propylene
G. M. Diamond, R. F. Jordan, J. L. Petersen, J. Am. Chem. Soc., 118, 8024
(1996).
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