Application

No.99
Chiral Phosphine Ligands
D2535 (R)-(S)-PPFA
[(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl-
ethylamine] (1)
100mg
D2536 (S)-(R)-PPFA
[(S)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl-
ethylamine] (2)
100mg

References

1) Asymmetric Grignard cross coupling
T. Hayashi, M. Konishi, M. Fukushima, T. Mise, M. Kagotani, M. Tajika, M. Kumada, J. Am. Chem. Soc., 104, 180 (1982).
T. Hayashi, M. Konishi, Y. Okamoto, K. Kabeta, M. Kumada, J. Org. Chem., 51, 3772 (1986).
2) Enantioselective vinylation of aldehydes with chiral β-silylphosphorus ylides
H. Iio, A. Fujii, M. Ishii, T. Tokoroyama, J. Chem. Soc., Chem. Commun., 1991, 1390.
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