Liquid Crystals & Related Compounds

Liquid crystals possess properties of both the liquid and solid phases, which results in the characteristic fluidity and optical birefringence (anisotropy) properties. Generally, the liquid crystal molecules consist of long chain moiety, rigid core and readily polarized functional groups. In some instances, they may form into plate shapes. In the liquid crystal state, the molecules are constrained to rotate, and line up into a regular array. Depending on how these molecules are arranged, the liquid crystal phases are classified as nematic, smectic or cholesteric phases. The regularity of these molecular arrangement is reflected in the anisotropic properties of permittivity and refractive index. Therefore, it is possible to control the optical property of the liquid crystal by changing the molecular arrangement electrically. The response speed of liquid crystals is fast due to the fluidity properties, and phase changes can easily occur both electrically and by heating.1) The application of liquid crystals for display purposes originated in HeiMeir when he and his co-workers (1968) reported using light scattering in the display material.2) Since then, Schiff base3) and azoxybenzene types4) were also developed; both have shown liquid crystalline state at room temperature. These developments have fundamentally contributed to today's prosperity within the liquid crystal industry. Some related compounds are shown as follows.

Cholesteryl Compounds

Cholesteryl Alkyl Carbonates

Carbonates

Phenyl Esters

Schiff Bases

Benzidines

Azoxybenzenes

Cyanobiphenyls & Analogs

Nematic Crystals

Cholesteryl Compounds

C1260 C1260 C0319 C0319 C0320 C0320
C0668 C0668 C0694 C0694 C0618 C0618
C0672 C0672 C0671 C0671 C0673 C0673
C0619 C0619 C0692 C0692 C0674 C0674
C0620 C0620 C0321 C0321 C0675 C0675
C0334 C0334 C0677 C0677 C0559 C0559
C0322 C0322 N0347 N0347 C0693 C0693
C0676 C0676 C0323 C0323 C0617 C0617
C0695 C0695 C0610 C0610
C1260 Cholesterol 2,4-Dichlorobenzoate
C0319 Cholesterol Acetate
C0320 Cholesterol Benzoate
C0668 Cholesterol Butyrate
C0694 Cholesterol Chloroformate
C0618 Cholesterol Decanoate
C0672 Cholesterol Enanthate
C0671 Cholesterol Formate
C0673 Cholesterol Hexanoate
C0619 Cholesterol Hydrocinnamate
C0692 Cholesterol Hydrogen Phthalate
C0674 Cholesterol Hydrogen Succinate
C0620 Cholesterol Laurate
C0321 Cholesterol Linoleate
C0675 Cholesterol Myristate
C0334 Cholesterol n-Caprylate
C0677 Cholesterol n-Valerate
C0559 Cholesterol Oleate
C0322 Cholesterol Palmitate
N0347 Cholesterol Pelargonate
C0693 Cholesterol Phenylacetate
C0676 Cholesterol Propionate
C0323 Cholesterol Stearate
C0617 Cholesterol trans-Cinnamate
C0695 Cholesteryl Bromide
C0610 Cholesteryl Chloride

Cholesteryl Alkyl Carbonates

C0716 C0716 C0719 C0719 C0717 C0717
C0715 C0715 C0720 C0720 C0718 C0718
B0264 B0264 C0725 C0725 B0256 B0256
C0721 C0721 C0691 C0691
C0716 Cholesterol Ethyl Carbonate
C0719 Cholesterol Isobutyl Carbonate
C0717 Cholesterol Isopropyl Carbonate
C0715 Cholesterol Methyl Carbonate
C0720 Cholesterol n-Amyl Carbonate
C0718 Cholesterol n-Butyl Carbonate
B0264 Cholesterol n-Heptyl Carbonate
C0725 Cholesterol n-Hexyl Carbonate
B0256 Cholesterol n-Nonyl Carbonate
C0721 Cholesterol n-Octyl Carbonate
C0691 Cholesterol Oleyl Carbonate

Carbonates

C0772 C0772 A0608 A0608 C0773 C0773
E0257 E0257 M0261 M0261 H0416 H0416
C0772 4-Carboxyphenyl n-Amyl Carbonate
A0608 Amyl 4-(4-Ethoxyphenoxycarbonyl)phenyl Carbonate
C0773 Butyl 4-Carboxyphenyl Carbonate
E0257 Ethyl 4-(4'-Ethoxyphenoxycarbonyl)phenyl Carbonate
M0261 Methyl 4-(4'-Ethoxyphenoxycarbonyl)phenyl Carbonate
H0416 n-Heptyl 4-(4'-Ethoxyphenoxycarbonyl)phenyl Carbonate

Phenyl Esters

B1108 B1108 H0766 H0766 B1091 B1091
B1586 B1586 H0810 H0810 B0375 B0375
B1092 B1092 P0896 P0896 P0897 P0897
P0898 P0898 A0842 A0842 S0146 S0146
S0016 S0016 B0077 B0077 B0063 B0063
I0416 I0416 P0305 P0305 H0797 H0797
H0218 H0218 B0075 B0075 S0017 S0017
S0274 S0274 S0018 S0018 S0129 S0129
T1370 T1370
B1108 2-Naphthyl Benzoate
H0766 4-(6-Hydroxyhexyloxy)benzoic Acid 4-Methoxyphenyl Ester
B1091 4-(Hexyloxy)phenyl 4-Butylbenzoate
B1586 4-Cyanophenyl 4-(3-Butenyloxy)benzoate
H0810 4-Cyanophenyl 4-Heptylbenzoate
B0375 4-Ethoxyphenyl 4-Butylbenzoate
B1092 4-n-Octyloxyphenyl 4-Butylbenzoate [Liquid Crystal]
P0896 4-n-Pentylbenzoic Acid 4'-n-Butoxyphenyl Ester
P0897 4-n-Pentylbenzoic Acid 4'-n-Hexyloxyphenyl Ester
P0898 4-n-Pentylbenzoic Acid 4'-n-Octyloxyphenyl Ester
A0842 4-Nitrophenyl Anthranilate
S0146 4-Nitrophenyl Salicylate
S0016 4-Octylphenyl Salicylate
B0077 Benzoic Acid 3-Hydroxyphenyl Ester
B0063 Benzoic Acid 4-Chlorophenyl Ester
I0416 Diphenyl Isophthalate
P0305 Diphenyl Phthalate
H0797 Phenyl 1-Hydroxy-2-naphthoate
H0218 Phenyl 4-Hydroxybenzoate
B0075 Phenyl Benzoate
S0017 Phenyl Salicylate
S0274 Salicylic Acid 4-tert-Butylphenyl Ester
S0018 Salicylic Acid p-Tolyl Ester
S0129 Salicylic Acid Salicylate
T1370 Terephthalic Acid Bis[4-(methoxycarbonyl)phenyl] Ester

Schiff Bases

B0253 B0253 B0252 B0252 C0744 C0744
C0743 C0743 C0742 C0742 E0254 E0254
E0240 E0240 E0262 E0262 B0374 B0374
H0419 H0419 M0605 M0605 B1713 B1713
M0583 M0583 M0604 M0604 M0588 M0588
M0602 M0602 B0255 B0255 M0603 M0603
B0261 B0261 B0372 B0372 B0250 B0250
M0581 M0581 M0275 M0275 M0582 M0582
B0875 B0875 B0871 B0871
B0253 4'-(Amyloxy)benzylidene-4-cyanoaniline
B0252 4'-Butoxybenzylidene-4-cyanoaniline
C0744 4'-Cyanobenzylidene-4-ethoxyaniline
C0743 4'-Cyanobenzylidene-4-n-butoxyaniline
C0742 4'-Cyanobenzylidene-4-n-hexyloxyaniline
E0254 4'-Ethoxybenzylidene-4-acetylaniline
E0240 4'-Ethoxybenzylidene-4-cyanoaniline
E0262 4'-Ethoxybenzylidene-4-n-butylaniline
B0374 4'-n-Butoxycarbonyloxybenzylidene-4-methoxyaniline
H0419 4'-n-Hexyloxybenzylidene-4-cyanoaniline
M0605 4-(4-Methoxybenzylidene)-4-hydroxyaniline
B1713 4-n-Butoxybenzylidene-4'-pentylaniline
M0583 4-[(4-Methoxybenzylidene)amino]azobenzene
M0604 4-[(4-Methoxybenzylidene)amino]benzonitrile
M0588 4-[(4-Methoxybenzylidene)amino]cinnamic Acid
M0602 4-[(4-Methoxybenzylidene)amino]cinnamic Acid Ethyl Ester
B0255 4-[(4-Methoxybenzylidene)amino]cinnamic Acid n-Butyl Ester
M0603 4-[(Methoxybenzylidene)amino]stilbene
B0261 Benzylidene-2-naphthylamine
B0372 N-(4-Butoxybenzylidene)-4-acetylaniline
B0250 N-(4-Methoxy-2-hydroxybenzylidene)-4-butylaniline
M0581 N-(4-Methoxybenzylidene)-4-acetoxyaniline
M0275 N-(4-Methoxybenzylidene)-4-butylaniline
M0582 N-(4-Methoxybenzylidene)aniline
B0875 Terephthalbis(4-fluoroaniline)
B0871 Terephthalbis(p-phenetidine)

Benzidines

B0890 B0890 B0874 B0874 B0878 B0878
B0890 N,N'-Bisbenzylidene-3,3'-dichlorobenzidine
B0874 N,N'-Bisbenzylidenebenzidine
B0878 p-Dianisal-3,3'-dichlorobenzidine

Azoxybenzenes

A0554 A0554 A0683 A0683 D1093 D1093
D1096 D1096 D0553 D0553 D1518 D1518
D1123 D1123 D1094 D1094 D1092 D1092
A1065 A1065
A0554 4,4'-Azoxydianisole
A0683 4,4'-Azoxydiphenetole
D1093 4,4'-Di-n-amyloxyazoxybenzene
D1096 4,4'-Di-n-butoxyazoxybenzene
D0553 4,4'-Di-n-dodecyloxyazoxybenzene
D1518 4,4'-Di-n-nonyloxyazoxybenzene
D1123 4,4'-Di-n-octyloxyazoxybenzene
D1094 4,4'-Di-n-propoxyazoxybenzene
D1092 4,4'-Dihexyloxyazoxybenzene
A1065 Diethyl Azoxybenzene-4,4'-dicarboxylate

Cyanobiphenyls & Analogs

A1828 A1828 H0812 H0812 C1606 C1606
C1551 C1551 C1550 C1550
A1828 4-(trans-4-Amylcyclohexyl)benzonitrile
H0812 4-Cyano-4'-heptylbiphenyl
C1606 4-Cyano-4'-heptyloxybiphenyl
C1551 4-Cyano-4'-n-pentyloxybiphenyl
C1550 4-Cyano-4'-pentylbiphenyl

Nematic Crystals

T0697 Liquid Crystal, TK-LQ 2040 Electric effect type, Mesomorphic range:20-40deg C [Nematic Liquid Crystal]
T0698 Liquid Crystal, TK-LQ 3680 Electric effect type, Mesomorphic range:36-80deg C [Nematic Liquid Crystal]
T0699 Liquid Crystal, TK-LQ 3858 Electric effect type, Mesomorphic range:38-58deg C [Nematic Liquid Crystal]

Literature

1) H. Hattori, Y. Kakuno, Yuki Gosei Kagaku Kyokaishi (J. Synth. Org. Chem. Jpn.), 1984, 42, 13.
2) G. H. HeilMeier, L. A. Zanoni, L. A. Barton, Proc. IEEE., 1968, 56, 1162.
3) H. Kelker, B. Scheurle, Angew. Chem., 1969, 81, 903.
4) R. Steinstrasser, et al., Tetrahedron Lett., 1971, 1929.


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