Structure
| TCI Product No. : | D0905 | |||||||||
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| Stock Status : |
Status at 07:00 a.m. on Sep 03, 2010 (JST) |
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| Purity / Analysis Method : | >99.0%(T) | |||||||||
| Storage : | ||||||||||
| M.F. / M.W. : | C24H16N2=332.40 | |||||||||
| CAS Number : | 1662-01-7 | |||||||||
| Related CAS Number : | ||||||||||
| MDL Number : | MFCD00004976 |
| mp : | 221 °C |
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Iron-catalyzed direct arylation of benzenes Typical procedure: To a vial is added Fe(OAc)2 (4.3 mg), bathophenanthroline (16.6 mg), and KOt-Bu (112 mg). To the vial is then added iodobenzene (102 mg) and benzene (3.9 g). The reaction was stirred vigorously at room temperature for 20 min and then at 80 ºC for 20 h. Following cooling, 2 mL of CH2Cl2/hexanes (1:1) is added, and the solution is filtered through silica pad. The pad then rinsed with 15 mL of CH2Cl2/hexanes (1:1). The combined solution is concentrated and the crude mixture is purified by column chromatography (eluent: hexanes) to give biphenyl (68.6 mg, 89 %) as a white solid. |
| Beilstein : | 23(5)10,274 |
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| RTECS# : | SF8427000 |
| TCI Product Literature : | |
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| Related Categories : |
Analytical Chemistry
Chelating Reagents
Phenanthrolines
Functional Materials Electroluminescence Synthetic Organic Chemistry Suzuki-Miyaura Cross-coupling Bases & Additives (for Suzuki-Miyaura Cross-coupling) Functional Materials Reagents for Solar Cell & Battery Research Research for Solar Cell Bipyridyls Functional Materials Reagents for Solar Cell & Battery Research Research for Solar Cell Semiconductors |