Structure
| TCI Product No. : | B1138 | |||||||||
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| Stock Status : |
Status at 07:00 a.m. on Sep 07, 2010 (JST) |
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| Purity / Analysis Method : | >98.0%(GC) | |||||||||
| Storage : | ||||||||||
| M.F. / M.W. : | C27H26P2=412.44 | |||||||||
| CAS Number : | 6737-42-4 | |||||||||
| Related CAS Number : | ||||||||||
| MDL Number : | MFCD00003050 |
| mp : | 63 °C |
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Synthesis of aromatic esters via Pd-catalyzed decarboxylative coupling with bidentate phosphine ligands Typical procedure: A 10 mL oven-dried Schlenk tube is charged with Pd(OAc)2 (0.005 mmol), 1,3-bis(diphenylphosphino)propane (0.0075 mmol), and potassium ethyl oxalate (0.75 mmol). The tube is evacuated and backfilled with argon. Bromobenzene (0.5 mmol) and 1-methyl-2-pyrrolidone (1.0 mL), are added by syringe at room temperature. The tube is then sealed and the mixture is allowed to stir under 1 atm of argon at 150ºC for 24 h (the tube is connected to the Schlenk line which is filled with argon so that CO2 can be released to air). |
| TCI Product Literature : | |
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| Related Categories : |
Synthetic Organic Chemistry
Suzuki-Miyaura Cross-coupling
Phosphine Ligands (for Suzuki-Miyaura Cross-coupling)
Synthetic Organic Chemistry Phosphines Synthetic Organic Chemistry Phosphine Ligands |